The Principals, over the years, are those men who strove day-in and day-out to develop the school to its position.
| Principals, over the Years | |||
| Years | Principal | Years | Principal |
| 1890 – 1897 | Fr. Joseph Gonsalves SJ | 1960 – 1962 | Fr. William Clement SJ |
| 1898 – 1904 | Fr. Joseph Savedra SJ | 1962 – 1963 | Fr. Freddie Britto SJ |
| 1905 – 1916 | Fr. Joseph Bramley SJ | 1963 – 1965 | Fr. Anthony Rehm SJ |
| 1917 – 1921 | Fr. Joseph Dias SJ | 1965 – 1968 | Fr. Vincent D’Souza SJ |
| 1922 – 1928 | Fr. Joachim Lima SJ | 1968 – 1973 | Fr. Walter D’Souza SJ |
| 1929 – 1935 | Fr. Joseph Dias SJ | 1973 – 1977 | Fr. Mathew Almeida SJ |
| 1936 – 1939 | Fr. Joachim Coelho SJ | 1977 – 1979 | Fr. Joseph Toscano SJ |
| 1940 – 1941 | Fr. Joseph Dias SJ | 1979 – 1992 | Fr. Agnelo Pinto SJ |
| 1942 | Fr. Joachim Abranches SJ | 1992 – 2004 | Fr. Jacob Carvalho SJ |
| 1943 | Fr. John A de Miranda SJ | 2004 – 2005 | Fr. G Rajendra SJ |
| 1944 – 1946 | Fr. Joachim Coelho SJ | 2005 – 2006 | Fr. Agnelo Pinto SJ |
| 1947 – 1949 | Fr. Irineu Lobo SJ | 2006 – 2011 | Fr. Gerald Furtado SJ |
| 1950 | Fr. Peter Mendonca SJ | 2011 – 2014 | Fr. Roland Coelho SJ |
| 1951 | Fr. Aloysius G Rego SJ | 2014 – 2015 | Fr. Alban D’Souza SJ |
| 1952 | Fr. Vincent D’Souza SJ | 2015 – 2017 | Fr. Basil Vago SJ |
| 1953 – 1954 | Fr. Aloysius D’Cruz SJ | 2017 | Fr. Roland Coelho SJ |
| 1955 – 1957 | Fr. Aloysius G Rego SJ | 2017 – 2020 | Fr. Pedro Rodrigues SJ |
| 1957 – 1958 | Fr. John A Lobo SJ | 2020 Onwards | Fr. Savio Abreu SJ |
| 1958 – 1960 | Fr. Robert Jacob SJ | ||
Prior to 1890, the succession began with Fr. Henry Charmillot SJ, who was followed by Fr. John Esseiva SJ, Fr. Henry Daling SJ, Fr. Paul Salinger SJ, Fr. Wilhelm Adams SJ, Fr. George Bridges SJ, Fr. George Waldman SJ, Fr. Charles Kreutzer SJ, Fr. Joseph Nueckel SJ, & then to Fr. Joseph Gonsalves SJ in 1890.
  |
  |
| Fr. Joseph Gonsalves SJ | Fr. Joseph Savedra SJ |
| 1890 – 1897 | 1898 – 1904 |
  |
  |
| Fr. Joseph Bramley SJ | Fr. Joseph Dias SJ |
| 1905 – 1916 | 1917 – 1921; 1929 – 1935; 1940 – 1941 |
  |
  |
| Fr. Joachim Lima SJ | Fr. Joachim Coelho SJ |
| 1922 – 1928 | 1936 – 1939; 1944 – 1946 |
  |
  |
| Fr. Joachim Abranches SJ | Fr. John A de Miranda SJ |
| 1942 | 1943 |
  |
  |
| Fr. Irineu Lobo SJ | Fr. Peter Mendonca SJ |
| 1947 – 1949 | 1950 |
  |
  |
| Fr. Aloysius G Rego SJ | Fr. Vincent D’Souza SJ |
| 1951; 1955 – 1957 | 1952; 1965 – 1968 |
  |
  |
| Fr. Aloysius D’Cruz SJ | Fr. John A Lobo SJ |
| 1953 – 1954 | 1957 – 1958 |
  |
  |
| Fr. Robert Jacob SJ | Fr. William Clement SJ |
| 1958 – 1960 | 1960 – 1962 |
  |
  |
| Fr. Freddie Britto SJ | Fr. Anthony Rehm SJ |
| 1962 – 1963 | 1963 – 1965 |
  |
  |
| Fr. Walter D’Souza SJ | Fr. Mathew Almeida SJ |
| 1968 – 1973 | 1973 – 1977 |
  |
  |
| Fr. Joseph Toscano SJ | Fr. Agnelo Pinto SJ |
| 1977 – 1979 | 1979 – 1992; 2005 – 2006 |
  |
  |
| Fr. Jacob Carvalho SJ | Fr. G Rajendra SJ |
| 1992 – 2004 | 2004 – 2005 |
  |
  |
| Fr. Gerald Furtado SJ | Fr. Roland Coelho SJ |
| 2006 – 2011 | 2011 – 2014; 2017 |
  |
  |
| Fr. Alban D’Souza SJ | Fr. Basil Vago SJ |
| 2014 – 2015 | 2015 – 2017 |
| Â |
 |
| Fr. Pedro Rodrigues SJ | Fr. Savio Abreu SJ |
| 2017 – 2020 | 2020 Onwards |